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Lecture Notes
Alan D. Earhart
= Southeast Community College • Lincoln, NE
Chapter 1 <= /div>
Chemistry: Matter and Measurement
John E. McMurry • Robert C. Fay=
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Fif= th Edition
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= Copyright © 2008 Pearson Prentice Hall, Inc.
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= Chapter 1: Chemistry: Matter and Measurement
= 9/23/2008
= Copyright © 2008 Pearson Prentice Hall, Inc.
= ‹#›
------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/pres.xml Content-Transfer-Encoding: quoted-printable Content-Type: text/xml; charset="utf-8" ------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/slide0105.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Ele= ctrolytes, Net Ionic Equations= , and Solubility
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 1/1
------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/master03_image001.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhEAIEAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALAIAAAAM AgQAgAAAAAAAAAIyRI6py+0Po5y02ouz3rz7D4biSH6AUabqyrbuC8fyTIdojef6zvf+DzQFh8Si 8YhMBgsAOw== ------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/slide0181.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/2
Some Ways That Chemical Reactions Occur
Acid-Base Neutralizat= ion Reactions: Processes in which an acid reacts with a base to yield water plus a salt.
H2O(l) + NaCl(aq)
HCl(aq) + NaOH(aq)
Precipitation Reactio= ns: Processes in which soluble reactants yield an insoluble solid product that falls out of solution.
2KNO3(aq) + PbI= 2<= /span>(s)
Pb(NO3)2(aq) + 2KI(aq)
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/3
Some Ways That Chemical Reactions Occur
Oxidation-Reduction (Redox) Reactions: Processes in which one or more electrons are transferred between reaction partners (atoms, molecules, or ions).
MgCl2(aq) + H2(g)
Mg(s) + 2HCl(aq)
------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/slide0182_image004.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlhSwEcAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALJcACgAb AAcAgAAAAAAAAAIdhI+poe0ZGGIU1Gtz3Hb7D4bYqJXfgx5RyhrSUQAAOw== ------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/slide0183.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/4
Electrolytes in Aqueous Solution
Electrolytes: Substances which dissolve in water to produce conducting soluti= ons of ions.
H2<= /span>O
Na1+(aq) + Cl1-= (aq)
NaCl(s)
A solution of NaCl conduct= s electricity because of the movement of charged particles (ions).=
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/5
Electrolytes in Aqueous Solution
Nonelectrolytes: Substances which do not produce ions in aqueous solutions= .
H2<= /span>O
C12H22O11= (aq)
C12H22O11= (s)
A solution of C12= H22= O11=  does not conduct electrici= ty because it contains no charged particles (ions).
C= 12H22O11 is sucrose (table sugar).
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/6
Electrolytes in Aqueous Solution
Weak Electrolytes: Compounds that dissociate to a small extent into ions when dissolved in water.
H1+(aq) + CH3<= /span>CO2<= /span>1-= (aq)
CH3CO2H(aq)
Strong Electrolytes: Compounds that dissociate to a large extent into = ions when dissolved in water.
K1+(aq) + Cl1-= (aq)
KCl(aq)
For a = 0.10 M solution, KCl is approximately 98% dissociated while CH3CO2H (acetic acid) is a little more than 1% dissociated.
The si= ze of the arrows indicate which side of the chemical equation the equilibrium lies = on.
The us= e of the equilibrium arrows is minimal until later chapters on kinetics and chemic= al equilibrium.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/7
Electrolytes in Aqueous Solution
Strong Acids: hydrochloric acid, hydrobromic acid, hydroiodic acid, perchloric acid, nitric acid, sulfuric acid.
Str= ong acids are strong electrolytes (which is why they are called strong acids!). These are typically called the 6 common strong acids. There are other strong acids.
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file:///C:/A7293655/c1210L15_files/slide0187.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/8
Electrolytes in Aqueous Solution
Ionic Compounds
Hyd= roxides are also ionic compounds.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter= 4/9
Electrolytes in Aqueous Solution
Weak acids
Any= acid that’s not a strong acid is considered to be a weak acid.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/10
Electrolytes in Aqueous Solution
Molecular Compounds
(other than any strong or weak electrolytes)
Any= molecular compounds which are not already classified (acids are molecular).
Whi= le water does dissociate to a small degree, we consider it to be a nonelectrolyte. The dissociation of water will be dealt with in a later chapter.
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3D"04_E01"
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/14
Aqueous Reactions and Net Ionic Equations
2KNO3(aq) + PbI= 2<= /span>(s)
Pb(NO3)2(aq) + 2KI(aq)
Molecular Equation: All substances in the chemical equation are written using their complete formulas as if they were molecules.
strong electrolytes
precipitate
Grante= d, all of the substances in the chemical equation are ionic compounds but it’s co= mmon to call this the molecular equation.
Pictur= es are useful especially with this reaction. Solutions of lead(II) nitrate and potassium iodide are colorless while the precipitate of lead(II) iodide is yellow.<= /font>
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/15
Aqueous Reactions and Net Ionic Equations
Ionic Equation: A= ll of the strong electrolytes are written as ions.
2K1+(aq) + 2NO3<= /span>1-=  (aq) + PbI= 2<= /span>(s)
Pb2+(aq) + 2NO3<= /span>1-=  (aq) + 2K1+(aq) = + 2I1-(aq)
2KNO3(aq)
Pb(NO3)2(aq)
2KI(aq)
Note t= he proper charges (as learned previously when writing ionic compound formulas).
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/16
Aqueous Reactions and Net Ionic Equations
Spectator Ions: I= ons that undergo no change during the reaction and appear on both sides of the reaction arrow.
2K1+(aq) + 2NO3<= /span>1-=  (aq) + PbI= 2<= /span>(s)
Pb2+(aq) + 2NO3<= /span>1-=  (aq) + 2K1+(aq) = + 2I1-(aq)
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/17
Aqueous Reactions and Net Ionic Equations
PbI2(s)
Pb2+(aq) + 2I= 1-= (aq)
Net Ionic Equation: Only the ions undergoing change are shown.
This d= oesn’t suggest that you can actually have a solution of iodide ion. The corresponding cations and anions are present but they are spectator ions.=
An aqu= eous solution that contains lead(II) ion when mixed with another one that contains iodi= de ion will typically produce a precipitate of lead(II) iodide.
------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/slide0193_image030.gif Content-Transfer-Encoding: base64 Content-Type: image/gif R0lGODlh/wAdAHcAMSH+GlNvZnR3YXJlOiBNaWNyb3NvZnQgT2ZmaWNlACH5BAEAAAAALKAACgAb AAcAgAAAAAAAAAIahI+poe0ZImIU1Gtz3Hb7D4bMQ3ZjWUromhQAOx== ------=_NextPart_01C91D67.AA0D11B0 Content-Location: file:///C:/A7293655/c1210L15_files/slide0194.htm Content-Transfer-Encoding: quoted-printable Content-Type: text/html; charset="us-ascii" Chemistry: McMurry and Fay, 5th Edition
Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/18
Precipitation Reactions and= Solubility Guidelines
1.A compound is probably soluble if it contains one of the following = cations:
Grou= p 1A cation: Li1+, Na1+, K1+, Cs1+
Ammo= nium ion: NH41+
2.A compound is probably soluble if it contains one of the following = anions:
Hali= de: Cl1-, Br1-, I1-
e= xcept Ag1+, Hg22+= , and Pb2+ compounds =
Nitrate (NO31-), perchlorate (ClO4<= /span>1-= ), acetate (CH3CO21-), sulfate (SO4<= /span>2-= )
e= xcept Ba2+, Hg22+= , and Pb2+ sulfates
Page 112
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/19
Precipitation Reactions and= Solubility Guidelines
Write the molecular, ioni= c, and net ionic equations for the reaction that occurs when aqueous solutions of AgNO3 and Na2CO3<= /span> are mixed.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/20
Precipitation Reactions and= Solubility Guidelines
Write the chemical formu= las of the products (use proper ionic rules).
Ag2CO3
AgNO3(aq)
+
Na2CO3(aq)
+
NaNO3
CB + AD
AB + CD
double replacement reaction
Write the molecular, ioni= c, and net ionic equations for the reaction that occurs when aqueous solutions of AgNO3 and Na2CO3<= /span> are mixed.
1.
Swap t= he cations to determine the possible products.
Pro= perly written products! Not: AgCO3 and Na2NO3.
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Copyright &c= opy; 2008 Pearson Prentice Hall, Inc.
Chapter 4/21
Precipitation Reactions and= Solubility Guidelines
Molecular Equation: Balance the equation and predict the solubility of each poss= ible product.
Ag2CO3(s) + 2NaN= O3<= /span>(aq)
2AgNO3(aq) + Na2CO3<= /span>(aq)
Contains a group 1A cation.
Neither the cation nor th= e anion is in the solubility list.
Write the molecular, ioni= c, and net ionic equations for the reaction that occurs when aqueous solutions of AgNO3 and Na2CO3<= /span> are mixed.
2.
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3D"04_U03p112"
Reacti= on of aqueous AgNO3 with aqueous Na2CO3 gives a white precipitate of Ag2CO3.
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